Systematic Studies
of Sodium γ-Octyl Aspartate to evaluate its Biodegradation, Surface Parameters,
Micellization Aspects and Thermodynamic Properties of its Binary Mixture using Electrolytes
Sharma Himani and Tyagi Rashmi
Res. J. Chem. Environ; Vol. 25(7); 34-48;
doi: https://doi.org/10.25303/257rjce3421; (2021)
Abstract
γ-octyl aspartate has been synthesized with 46.2% yield. The optimized conditions
for esterification of aspartic acid and n-octanol are 24 hours duration and 1:1
molar ratio of reactants (aspartic acid: n-octanol). FT-IR, 1H NMR and CHNS element
analysis techniques are used for structure elucidation of γ -octyl aspartate. Surface/
interfacial studies, micellization aspects, thermodynamic parameters, biodegradability
and binary salt behaviour of sodium γ-octyl aspartate have been studied.
The CMC of synthesized surfactants was 0.0078 mol/L, whereas minimum surface area
per surfactant molecule was calculated as 29.49 Å2m2; calculated aggregation number
was 34 and micelle radius (r) found to be 1.40 nm. The degree of counter-ion dissociation
(α) was determined to be 0.86. Thermodynamic parameter - standard free energy of
adsorption (ΔG0ads) was calculated as -18.70 kJ/mol. The shape of micelle of synthesized
surfactant was noticed to be spherical but during binary studies in some cases,
it was found to be cylindrical. OECD and Winkler’s method were used to determine
biodegradation of sodium γ-octyl aspartate found to be 95.1 %.
