Synthesis, Characterization
and Electrical conductivities of the Complexes of Nickel(II), Copper(II) and Zinc(II)
with 2,5-diamino-3,6-dichloro-1,4-benzoquinone
Kushwaha A., Dwivedi Smriti and Prasad R.L.
Res. J. Chem. Environ.; Vol. 28(5); 24-29;
doi: https://doi.org/10.25303/285rjce024029; (2024)
Abstract
Complexes of the type [M(dadb)] (M = Ni(II), Cu(II) and Zn(II)) with ligand 2,5-diamino-3,6-dichloro-1,4-benzoquinone
(dadb) have been synthesized and characterized by microanalysis, magnectic susceptibility,
electronic, IR, ESR spectroscopy techniques, thermogravimetric analysis (TG), differential
thermal analysis (DTA), X-ray powder diffraction (XRD) and solid phase conductivity
measurements.
The room temperature ESR spectra of Cu(II) complex yield ‹g› values, characteristics
of square planar geometry. The solid state electrical conductivities of the complexes
increase as the temperature increases from 311-383 K, with a band gap of 0.11- 0.21
eV, indicating their semiconducting behaviour.
