Research Journal of Chemistry

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Biogenic Synthesis of Potassium Nanoparticles from Artocarpus hirsutus Leaf Extract: A Novel Nanofertilizer for Enhanced Growth of Vigna radiata

Peddi Pavani

Res. J. Chem. Environ.; Vol. 29(3); 95-106; doi: https://doi.org/10.25303/293rjce950106; (2025)

Abstract
The utilization of potassium nanoparticles as a novel nanofertilizer synthesized through biogenic means represents a significant advancement in agricultural technology. Potassium is a vital nutrient for plants, playing essential roles in growth, yield, metabolism, enzymatic activity regulation and overall physiological functions. In this study, potassium nanoparticles were synthesized using Artocarpus hirsutus plant leaf extract and their efficacy in promoting growth in Vigna radiata (green gram) plants was investigated. Characterization of the synthesized nanoparticles revealed their morphological and stability-related parameters. Transmission electron microscopy (TEM) measurements indicated a size range of 70 nm for the potassium nanoparticles, while Scanning electron microscopy (SEM) analysis reported a size of 400 nm. The elemental analysis using energy dispersive X-ray (EDX) confirmed the presence of potassium (K) in the synthesized nanomaterial, with approximately 40% potassium content.

In laboratory experiments, five different concentrations of nano potassium (ranging from 100 μg/mL to 1000 μg/mL) were tested alongside a blank control (with no external potassium supplement) for seed germination and plant growth activity. The results demonstrated that nano potassium-treated plants exhibited enhanced growth and yield compared to the control group. Additionally, plants sprayed with nano potassium showed efficient utilization of exchangeable potassium from the soil, leading to minimal potassium loss through leaching. The green synthesised KNPs show effective anti-oxidant activity. Overall, this study presents a promising potassium nano fertilizer that effectively promotes the growth and yield of Vigna radiata plants without causing any undesirable harmful effects on the environment.